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A zinc–iodine single flow battery (ZISFB) with super high energy density, efficiency and stability was designed and presented for the first time. In this design, an electrolyte with very high concentration (7.5 M KI and 3.75 M ZnBr 2) was sealed at the positive side. Thanks to the high solubility. . A long chain polycation (Pah⁺) is propos ed to simultaneously regulate Zn anode deposition, mitigate side reactions and stabilize iodine cathode chemistry. The iodophilic and low diffusivity nature of Pah enables effective polyiodide immobilization, suppressing the shuttle effect and ensuring a.
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